DETAILED MICROSTRUCTURAL STUDIES OF AMORPHOUS AL-NI-SI AND AL-NI-SI-CU ALLOYS DURING CRYSTALLIZATION

Authors

  • Yana Mourdjeva Institute of Metal Science, Equipment, and Technologies with Hydro- and Aerodynamics Centre “Acad. A. Balevski” at the Bulgarian Academy of Sciences, Materials Testing and Analyses (BG)
  • Kateryna Valuiska Institute of Metal Science, Equipment, and Technologies with Hydro- and Aerodynamics Centre “Acad. A. Balevski” at the Bulgarian Academy of Sciences, Materials Testing and Analyses (BG)
  • Yoanna Kostova Institute of Metal Science, Equipment, and Technologies with Hydro- and Aerodynamics Centre “Acad. A. Balevski” at the Bulgarian Academy of Sciences, Materials Testing and Analyses (BG)
  • Vanya Dyakova Institute of Metal Science, Equipment, and Technologies with Hydro- and Aerodynamics Centre “Acad. A. Balevski” at the Bulgarian Academy of Sciences, Materials Testing and Analyses (BG)

DOI:

https://doi.org/10.17770/etr2024vol3.8166

Keywords:

amorphous, nanocrystalline, phase analysis

Abstract

Two types of rapidly solidified ribbons were obtained from the systems Al-Ni-Si and Al-Ni-Si-Cu. By XRD, TEM and DSC analysis the ribbons were proved to be amorphous. By annealing at 350⁰C nanocrystalline alloys were obtained. It was found that when the amorphous alloys are annealed at 190⁰C and 220⁰C, an unknown metastable hexagonal phase is presented, which could not be identified when annealing at 350⁰C is provided. Both studied alloys Al74Ni16Si10 and Al74Ni15Si9Cu9 show that when annealed at 190°C a residual amorphous phase is observed. It is located mainly at the phase boundaries.

Supporting Agencies
This study is funded by the project “Study of the rheological and corrosion behavior of amorphous and nanocrystalline aluminum-based alloys”, Contract with BNSF №KP-06-H37/13 of 06 December 2019.

Downloads

Download data is not yet available.

References

B.-J. Yang, J.-M. Yao, Y.- S. Chao, J.-Q. Wang, E. Ma, “Developing aluminum-based bulk metallic glasses, “ Philos. Mag., vol. 90, 2010, p.p. 3215–3231.

S. Pauly, S. Gorantla, G. Wang, U. Kühn, J. Eckert, “Transformation-mediated ductility in CuZr-based bulk metallic glaases,” Nat. Mater., Vol. 9, 2010, p.p. 473–477.

S.–Y. Kim, G.-Y. Lee, G.-H. Park, H.-A. Kim, A.-Y. Lee, S. Scudino, K.-G. Prashanth, D.-H. Kim, J. Eckert, M.-H. Lee, “High strength nanostructured Al based alloys through optimized processing of rapidly quenched amorphous precursors,” SCIENTIFIC REPORTS, vol. 8, 2018, p. 1090, DOI:10.1038/s41598-018-19337-7.

J. Ma, F. Ren, G. Wang, X. Yi, Y. Li, J. Wen, “Electrochemical performance of melt-spinning Al-Mg-Sn based anode alloys,” Int. J. Hydrogen Energy, vol. 42, 2017, p.p. 11654–11661.

K. W. Richter, H. Ipser, “The Al–Ni–Si phase diagram between 0 and 33.3 at.% Ni,” Intermetallics, vol. 11, 2003, p.p. 101–109

G. Beuers, C. Batzner, H.L. Lukas, In: Petzow G, Effenberg G, editors. Ternary alloys, vol. 7, 1993. p. 467

Mgr. J. Zigo, “Local structure in rapidly-quenched al-si based systems,” Dissertation Thesis, 2017.

O.S. Muratov, O.S. Roik, V.P. Kazimirov, N.V. Golovataya, V.K. Nosenko, G.M. Zelinskaya, T.M. Mika, V.E. Sokol'skii, “X-ray diffraction studies of the Ni–Si and Al–Ni–Si melts,” Journal of Molecular Liquids 200, 2014, p.p. 213–222

M. Gögebakan, M. Okumus, “Structure and crystallization kinetics of amorphous Al–Ni–Si alloy,” Materials Science-Poland, Vol. 27, No. 1, 2009, p.p. 78–87

J. M. Legersy, M. Audier , P. Guyot “Characterization and Kinetics of the Crystallization of AI-Ni-Si Amorphous Alloys,” Materials Science and Engineering, 97, 1988, p.p. 385-390.

V. Dyakova, Y. Mourdjeva, H. Spasova, G.Stefanov, Y. Kostova, “Effect of Cu as Мinority Аlloying Еlement on Glass Forming Ability and Crystallization Behavior of Rapidly Solidified Al-Si-Ni Ribbons, ” Environment. Technology. Resources. Rezekne, Latvia Proceedings of the 14th International Scientific and Practical Conference. Vol. 3, 2023, p.p 69-73

V. Dyakova, G. Stefanov, I. Penkov, D. Kovacheva, N. Marinkov, Y. Mourdjeva, S. Gyurov, “Influence of Zn on Glass Forming Ability and Crystallization Behaviour of Rapidly Solidified Al-Cu-Mg (Zn) alloys,” J. Chem. Technol. Metall., vol. 57, 2020, p.p. 622–630.

J.-H. Perepezko, R.-J. Hebert, “Amorphous aluminium alloys—Synthesis and stability,” JOM, vol. 54, 2002, p.p. 54, 34–39.

T. Egami, Y. Waseda, “Atomic size effect on the formability of metallic glasses,” J. Non-Cryst. Solids, vol. 64, 1984, p.p. 113–134.

X. Xue-Kui, T.-S. Magdalena, L. Yan-Hui, W. Wei-Hua, W. Yue, “Structural changes induced by microalloying in Cu46Zr47−x Al7Gdx metallic glasses,” Scr. Mater., vol. 61, 2009, p.p. 967–969.

K.L. Sahoo, R. Sahu, “Glass transition and crystallization of Al– Ni–La based metallic glasses studied by temperature modulated DSC”, Journal of Non-Crystalline Solids, 365, 2013, pp. 33-36

Downloads

Published

2024-06-22

How to Cite

[1]
Y. Mourdjeva, K. Valuiska, Y. Kostova, and V. Dyakova, “DETAILED MICROSTRUCTURAL STUDIES OF AMORPHOUS AL-NI-SI AND AL-NI-SI-CU ALLOYS DURING CRYSTALLIZATION”, ETR, vol. 3, pp. 166–169, Jun. 2024, doi: 10.17770/etr2024vol3.8166.