DETAILED MICROSTRUCTURAL STUDIES OF AMORPHOUS AL-NI-SI AND AL-NI-SI-CU ALLOYS DURING CRYSTALLIZATION
DOI:
https://doi.org/10.17770/etr2024vol3.8166Keywords:
amorphous, nanocrystalline, phase analysisAbstract
Two types of rapidly solidified ribbons were obtained from the systems Al-Ni-Si and Al-Ni-Si-Cu. By XRD, TEM and DSC analysis the ribbons were proved to be amorphous. By annealing at 350⁰C nanocrystalline alloys were obtained. It was found that when the amorphous alloys are annealed at 190⁰C and 220⁰C, an unknown metastable hexagonal phase is presented, which could not be identified when annealing at 350⁰C is provided. Both studied alloys Al74Ni16Si10 and Al74Ni15Si9Cu9 show that when annealed at 190°C a residual amorphous phase is observed. It is located mainly at the phase boundaries.
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